So - how did it go?
Well, like the Curates Egg, it's 'good in parts'
Putting it back together I was concerned that lining up the two pistons and bores might have been an issue, so initially I put the packing glands on the pistons to leave less to align. This was a mistake! Once I put the pump casting back on it's studs it proved impossible to start the threads that pull the packing glands into the cylinders. So the pump casting had to be removed, glands loosely screwed in, then the casting put back and bolted to the crankcase. After that it was just a case of putting all the gubbins back on facing in the right directions!
Starting up, the engine leapt into life, and the pump started pumping - no high pressure back feed to the water inlet, so that at least is cured. However the pressure switch is again playing up. It started switching the clutch off at about 15 bar - I did tweak the spool nuts but I couldn't get it to be consistent in where it switched off the clutch.
Pump is producing pressure up to whatever I set the relief valve to (yes I tweaked that as well!) it's just that bally pressure switch

The hot water side is working, producing boiling water with no problem - the flame failure circuit is a bit iffy - probably needs the window on its cadmium sulphide cell cleaning.
I am very tempted to design a replacement pressure switch arrangement if I can find anything suitable - stuff in this pressure range tends to get a bit pricey. I suspect that the current piston mechanism and it's seals are perhaps getting a bit tired and not responding as fast as they should. Remember, it's always been temperamental.