Chris,
To expand, my concerns would be, quality of the original boiler and what it's made from. Quality of the solder joints, might have been fine when new, but what of now.
And lastly, general corrosion. You don't know what's been eaten away inside?
I'm guessing that to test you would need a high pressure compressor and gauges to suit. Oh and some sort of safety cage. I doubt our workshop compressors generate high enough pressures? I don't really know, but that's what I would want to do, test it well and above any working pressures before contemplating using it.
I understand boiling water generates some very high pressures when sealed in a container. It takes little extra heat to send it climbing at a frightening rate.