I have no experience of CNC but I'm reasonably ok with maths... I can't see where in your OP you mention the spoke width you need and if they're straight or tapered spokes?
Let's assume an 8mm spoke for a moment. It seems to me that if your wheel centre is 0,0, and your cutter is 5mm, you need to start at something like 6.5,9 and go down the +y direction to 6.5, (radius minus 7.5) for your first cut outwards (assuming straight spoke). That leaves 6.5-(5/2) = 4mm for half the spoke width and 7.5-(5/2) = 5mm for the rim. (I did NOT calculate the start point for an exact 7mm boss, the y=9 in that start coordinate would need tweaking)
Instead of trying to calculate the other side of the arc, if you can rotate the entire coordinate system about the origin and repeat cuts as you seem to suggest, perhaps it might be easier to just cut the other side of the spoke (ie -6.5, 9 to -6.5, r-7,5)? IE instead of cutting the whole wedge out between rotation cycles, cut a spoke and an arc.
Even if you don't translate CAD vectors into G-code by computer, it would still seem worth drawing exactly what you want in something like DraftSight first (warning: steep learning curve ahead!) or even Inkscape (much easier, not a CAD package, but pretty decent for drawing accurate diagrams). (both are free)