Graz,
Dovetails are usually machined and come in a variety of angles. It is normal practice to cut them on the mill using a dovetail cutter.
The two most popular are 45 and 60 degrees for slides, but as I said, they can come in other flavours.
As mentioned before, when changing angles, good thought has to be given to the gib strip, and you might find, once the new dovetail is cut by cutting away the old one, the gib strip could end up being too wide for safe use.
Bogs